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due to plastics tool has weight light, tough property good, molding easy. cost low and other advantages, therefore in industrial and day use product in, 越 越 more use plastics 代替玻璃, especially used for optical device and packaging industrial 方面, development is speed. is due to requirements its transparent property need good, wear resistant parts need high, impact resistant tough parts need good, therefore for plastics formed 份, injection molding process process, equipment, mold and other, need as a large amount of as, ensure this used for 代替玻璃 plastics ( below/following transparent plastics ), surface quality good, from to use requirements.
currently market upper generally use transparent plastics has polymethyl methacrylate (PMMA) (即俗称亚 add force or has machine 玻璃, 代号PMMA), polycarbonate (PC) (代号PC), terephthalic acid ethylene glycol 脂(代号PET), transparent nylon. AS( propylene 睛一苯 ethylene copolymer ), polysulfone (PSU) (代号PSF) and other, its in 我们接触 most more is PMMA, PC and PET三 types plastics, due to has 限, lower 面就以 this types plastics is 例, transparent plastics features and injection molding process.
一, transparent plastics property can
transparent plastics 首先必 must has high transparency degree, its need has strong/high degree and wear resistance, can impact resistant, heat resistant property need good, chemical resistance need excellent, water absorption need small, has this can in use in, can meet/satisfy transparent degree requirements long 久不变, lower 面列出 table/sheet l, comparison lower PMMA, PC and PET property can.
table/sheet 1: transparent plastics property can comparison
|
property can |
density
(g/am2)
|
resistant strong/high degree
(MPa)
|
缺口 impact
(J/m2)
|
transparent degree
(%)
|
deformation temperature degree
(℃)
|
允许含 water amount |
shrinkage rate |
wear resistance |
resistant chemical property |
|
PMMA |
1.18 |
75 |
1200 |
92 |
95 |
0.04 |
0.5 |
差 |
良 |
|
PC |
1.20 |
66 |
1900 |
90 |
137 |
0.02 |
0.6 |
in |
良 |
|
PET |
1.37 |
165 |
1030 |
86 |
120 |
0.03 |
2 |
良 |
excellent |
注: (1)因 product types more, this is 取平均 value, different product types data has 异.
(2)PET data ( machine 械方面) is tensile rear data.
from table/sheet 1 data can 知PC is relatively selection, 但主于 its raw materials and injection molding process relatively difficult, therefore still selection PMMA is 主, ( for generally requirements products ), 而RET due to need tensile can to good mechanical properties, therefore more in packaging, container in use.
二, transparent plastics injection molding process in attention/notes issues
transparent plastics due to light transmittance need high, requirements plastics products surface quality requirements 严格, can has 任何斑纹, gas 孔, 泛白, 雾晕, black spots, color, gloss and other defect, in injection molding process for raw materials, equipment, mold, product design, need separation attention/notes and 提出严格甚至特殊 requirements. its due to transparent plastics more is melting point high, flow property 差, therefore is ensure product surface quality, need in relatively high temperature degree, injection pressure, injection speed degree and other process parameters as fine micro adjustment, make plastics can 充满 模, also generate internal stress 而引起 product deformation and cracking.
lower its in raw materials 准备, for equipment and mold requirements, injection molding process and product raw materials 处理几方面, 谈谈应 attention/notes 事项.
(一) raw materials and drying due to in plastics in has 任何一点杂质, can can effect/influence product transparent degree, therefore and 储存, 运输, add material process in, must attention/notes 密封, ensure raw materials dry 净. especially is raw materials in has water separation, add hot rear 会引起 raw materials 变质, therefore need drying, in injection molding 时, add material must use drying material 斗. also need attention/notes is drying process in, 输入 空 gas most good 应经 滤, remove wet, ensure 不会污染 raw materials. its drying process table/sheet 2,
table/sheet 2, transparent plastics drying process:
|
process |
drying temperature degree (℃) |
drying time (h) |
material thick degree (mm) |
备注 |
|
PMMA |
70~80 |
2~4 |
30~40 |
using/adopting hot ring drying |
|
PC |
120~130 |
>6 |
<30 |
using/adopting hot ring drying |
|
PET |
140~180 |
3~4 |
|
using/adopting drying add material plant/unit is 佳 |
(二) machine 筒, screw and its parts 清洁
is anti raw materials and in screw and parts 凹陷处存 has material or 杂质, especially heat stabilized property resin in, therefore in use front, machine rear application screw agent dry parts, make its viscous has 杂质, has screw agent 时, can use PE, PS and other resin screw. 当临时停 machine 时, is anti raw materials in high temperature lower time long, understanding drop, will drying machine and machine temperature degree reduce, PC, PMMA and other machine temperature degree need drop 至 160℃ below/following. ( material temperature degree for/regarding PC应 drop 至100℃ below/following )
(三) in mold design upper attention/notes issues (包括 product design )
is anti 止出现回 flow 不畅, or cooling 不均造 formed plastics molding defect, generate surface defects and 变质, generally in mold design 时, attention/notes below/following 几点.
a)壁 thick amount uniform 一致, demolding degree need large;
b) 渡部 separation 应逐步. slip 渡, anti has 尖角. generate, especially is PC product 一定不 need has 缺口;
c) gate. runner can can wide large, coarse short, according to shrinkage cold process gate 位置, necessary 时 应 add cold material 井;
d) mold surface light 洁, coarse degree low ( most good low 于0.8);
e)排 gas 孔. must 足够, and 时排出空 gas and 熔 体 in gas 体;
f) remove PET outer, thick need thin, generally small 于lmm.
(四) injection molding process 方面应 attention/notes issues (包括 injection molding machine requirements )
is decrease/reduce internal stress and surface quality defect, in injection molding process 方面应 attention/notes below/following 几方面 issues.
a)应 selection specialized screw, belt/tape mono temperature 控射咀 injection molding machine;
b) injection temperature degree in plastics resin separation understanding front lower, use relatively high injection wet degree;
c) injection pressure: generally relatively high, 以克服熔 material viscosity large defect, pressure high generate internal stress formed demolding difficult and deformation;
d) injection speed degree: in meet/satisfy 充模 情况 lower, generally low, most good can using/adopting slow - fast - slow more grade 注 射;
e) holding pressure time and molding cycle: in meet/satisfy product 充模, generate 凹陷, bubbles lower; amount short, amount decrease low material in machine 筒停留 time;
f) screw speed and back pressure: in meet/satisfy quality front lower, amount low, anti generate understanding drop can can;
g) mold temperature degree: products cooling good bad, for quality effect/influence large, therefore mold temperature need can control its process, has can can 话, mold temperature high good.
(五) other issues
due to is need anti upper surface quality 恶化, generally injection molding amount less use demolding agent; use use material large 于 20%.
for/regarding remove PET outer, products 都应进行 rear 处理, remove internal stress, PMMA应 in 70-80T hot ring drying 4 small 时; PC应 in 清洁空 gas, 甘油. liquid 体石腊 and other add hot 110-135℃, time product 而定, most high need 10 more small 时. 而PET必 must di toward tensile 工序, can to good mechanical properties.
三, transparent plastics injection molding process
(一) transparent plastics process features: remove above issues, transparent plastics has process property, separation lower:
1, PMMA process features PMMA viscosity large, flow property 稍差, therefore must high material temperature, high injection pressure injection molding 才行, its in injection temperature degree effect/influence large injection pressure, injection pressure improve/increase, has improvement product shrinkage rate. injection temperature degree scope/range relatively wide, melt temperature degree is 160℃, separation understanding temperature degree 达270℃, therefore material temperature adjustment scope/range wide, process property relatively good. improvement flow property, can from injection temperature degree 手. impact property 差, wear resistance good, easy 划花, easy 脆裂, improve/increase mold temperature, improvement cold process, this defect.
2, PC process features
PC viscosity large, melt material temperature degree high, flow property 差, 回此必 must relatively high temperature degree injection molding (270-320T之 间), versus for material temperature adjustment scope/range relatively narrow, process property 不如PMMA. injection pressure for flow property effect/influence relatively small, viscosity large, still need relatively large injection pressure, versus is anti internal stress generate, holding pressure time need amount short. shrinkage rate large, dimensions stability, product internal stress large, easy cracking, therefore use improve/increase temperature degree is pressure improvement flow property, and from improve/increase mold temperature degree, improvement mold structure and rear decrease/reduce cracking can can. injection speed degree low 时, gate easy 生波纹 and other defect, 放射咀 temperature degree need mono control, mold temperature degree need high, runner, gate retardant force need small.
3, PET process features
PET molding temperature degree high, material temperature adjustment scope/range narrow (260-300℃), 但熔化 rear, flow property good, process property 差, 且往往 in in need add anti plant/unit. machine strong/high degree and property can injection rear high, must through tensile and modified can improvement property can. mold temperature degree control, is anti warpage. deformation important factors, therefore using/adopting hot runner mold. mold temperature degree high, 否则会引起 surface gloss and demolding difficult.
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