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antioxidant selection 原则, main/primary product introduction
plastics processing in add a small amount of antioxidant, can retardant or aging process, from long plastics products use lifespan.
selection antioxidant 时, main/primary according to plastics material types type and Model/Grade, processing equipment and process conditions, its it chemical additives product types and add amount, products use ring and and other factors comprehensive 确定.
selection industrial applications antioxidant basic below/following 原则.
versus property
plastics polymer and antioxidant versus property relatively 差, usually is in high temperature lower will antioxidant and polymer melt combined, polymer solid will antioxidant separation versus in polymer separation in 间. in formulation use amount scope/range inner, antioxidant in processing temperature degree lower need melt. need especially attention/notes, design formulation 时, selection solid antioxidant, light stabilizer melting point or upper 限, low plastics polymer processing temperature degree.
迁移 property
plastics products, especially is surface and ratio (or quality ratio)数 value relatively small products, oxidation main/primary in products surface, this need antioxidant 连续不断 from plastics products internal to products surface 而发挥 function. if toward products surface speed degree fast, amount large, antioxidant need to products surface ring in, or expand dispersion agent and products surface its it in loss 失, this type of loss 失事实 upper is can 避免, design formulation add 以考虑. antioxidant product types has selection 余 时, selection molecular weight versus for relatively large, melting point relatively high product types, and need most use ring is front 提确定 antioxidant use amount.
stability property
antioxidant in plastics material in maintain stability, in use ring lower and high temperature processing process in loss less, color or color, separation understanding (remove used for processing heat stabilized function antioxidant outer), and its it additives 发生不利 chemical 应, 不腐蚀 machine equipment, easy by products surface its it material 质 抽提.
processing property
plastics products processing 时, add antioxidant for resin degree and screw 转矩都 can can 发生改变. antioxidant for resin melt scope/range if versus relatively large, generate antioxidant or screw phenomenon. antioxidant melting point low processing temperature degree 100℃ above 时, will antioxidant made formed masterbatch, again and resin mixed combined processing products, 以避免因偏流造 formed products in antioxidant distribution and processing output/production volume decline.
ring and property
antioxidant 应无毒 or low 毒, powder or low powder 尘, in plastics products processing manufacturing and use in for 人体无 has function, for material, material 无危害, for gas, 土壤, water 系 无污染.
for use film food packaging box/case, toys, one-time property liquid and other or 直接接触 food, product, medical device tool has plastics products, not only selection already through USA food and material tube/pipe 理局(FDA)检验并许 can, or 欧共体委员会 method 令允许 antioxidant product types, but also add amount 应严格 control in most large 允许限 degree inner.
main/primary product
★ antioxidant 1010
white flow property powder 末, melting point 120~125℃, property relatively low, is types relatively good antioxidant. in PP in application relatively more, is types heat stabilized property high, non combined high temperature conditions lower use additives. another, can used for its it large more resin. generally add amount large 于0.5%.
★ antioxidant 1076
white or micro crystallization powder 末, melting point is 50~55℃, 无毒, solvent water, can solvent 于苯, ketone, and ester type and other solvent agent. can as is PE, PP, PS, PVC, PA, ABS and acrylic and other resin antioxidant. tool has resistant oxygen property good, property small, resistant and other features. generally use amount large 于0.5%.
★ antioxidant 168
white crystallization powder 末, melting point 183~187℃. color, 不污染, resistant property good. antioxidant, and antioxidant 1010 or 1076复配 has very good 协同效应. can used for PE, PP, PVC, PS, PA, PC, ABS and other.
★ antioxidant CA
white crystallization powder 末, melting point 180~188℃,毒 property low, solvent ketone, alcohol, and acid ester. combined 于PP, PE, PVC, ABS and PA resin. generally use amount ultra- 0.5%.
★ antioxidant 164
white or shallow color crystallization powder or sheet/slice material. melting point in 70℃, in 260℃ left right, 无毒. used for multiple resin in, applications 广泛. more combined used for food packaging molding use material (PP, PE, PVC, ABS, polyester and PS). generally use amount is 0.01%~0.5%.
★ antioxidant DNP
shallow color powder 末, melting point 230℃ left right, easy solvent amine and 硝基苯 in, solvent water. combined 于PE, PP, HIPS and ABS resin, remove tool has resistant oxygen can outer, also has relatively good heat stabilized function and made copper, metal effect/influence. generally use amount ultra- 2%.
★ antioxidant DLTP
white crystallization powder 末, melting point in 40℃ left right, property low, solvent water, can solvent 于苯, chlorine carbon, ketone. used for PE, PP, ABS and PVC resin antioxidant, can products heat resistant property and resistant oxygen property. generally use amount is 0.05%~1.5%.
★ antioxidant TNP
shallow color viscous liquid 体, solid low 于-5℃沸点 large 于105℃, 无味, 无毒, solvent water, solvent ketone, alcohol, and chlorine carbon. combined 于PVC, PE, PP, HIPS, ABS, polyester and other resin, high temperature in resistant oxidation property can high. use amount ultra- 1.5%.
★ antioxidant TPP
shallow color transparent liquid 体, solid 点19~24℃, 沸点220℃, solvent alcohol, 苯, ketone. combined 于PVC, PS, PP and ABS resin antioxidant. use amount ultra- 3%.
★ antioxidant MB
淡黄 color powder 末, melting point large 于285℃, solvent alcohol, ketone, acid ester, solvent water and 苯. combined 于PE, PA and PP resin antioxidant;不污染, color, can used for white or color products. use amount ultra- 0.5%.
★ antioxidant 264
appearance is white crystallization 体. melting point 69-71℃; versus for density 1.048(20℃);折 light rate 1.4859(75℃). normal temperature lower solvent alcohol, alcohol, alcohol, ketone, ether, 苯;不 solvent water, 甘油, alcohol. 无臭, 无味, tool has good heat stabilized property. as general purpose type type antioxidant. used for polymer/macromolecule material in.
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