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nylon 66 industry analysis 调查 report

Date: 2019-11-17 10:00 Views: 3130 Source: Internet

 1, brief introduction

nylon 66 also 称锦纶66, polyamide (PA) -66, poly already hexamethylenediamine

 

nylon 66 structure 式

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features:

  • resistant force cracking property good

  • wear resistance most good polyamide (PA)

  • heat resistant property good, self-extinguishing property material

  • 自 lubricated property good, 仅次于 PTFE and polyoxymethylene (POM)

  • oil resistant property 极佳, can solvent 于苯酚 and acid

  • machine strong/high degree high, chemical stability property good

  • add carbon can improve/increase its weather resistance

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2, development history

 

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3, production and molding technology

 

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molding technology: large has 88% nylon 66 through injection molding processing formed various made parts, 约12% nylon 66 则 through extrusion, blow molding and other molding processing formed versus products.

 

drying 处理: if processing front material is 密封, that 么就没 has necessary drying. if container by 打开, that 么建议 in 85C hot gas in drying 处理. if wet degree large 于0.2%, also need 进行105C, 12 small true drying.

熔化 temperature degree: 260~290C. for additives product is 275~280C. temperature degree 应避免 high 于300C.

mold temperature degree: 建议80C.

injection pressure: usually in 750~1250bar, 取决于材 material and product design.

injection speed degree: high speed ( for/regarding reinforcement type material low 一 ).

runner and gate: due to PA66 solid time very short, therefore gate non important. gate 孔径不 need small 于0.5*t( this 里t is parts thick degree ). if use hot runner, gate dimensions ratio use runner small 一, is hot runner can 够帮助 retardant material solid. if use 潜入式 gate, gate most small 直径应当 is 0.75mm.

 

4, nylon 66 industry chain

 

 

mono supply 商

nylon 66 raw materials

nylon application

China 石化

辽通 chemical industry

齐翔腾达

Bluestar new 材

Shenma 实业

天利 high new

沈 cationic chemical industry and other

USA DuPont

Shenma 实业

Netherlands DSM

BASF

France 罗 亚

Toray

Asahi Kasei

厦门东纶

nylon 66 main/primary used for automotive, machine industrial, electronics electrical appliances, precision device and other field/area. from most applications 看, automotive industry consumption nylon 66占第一位, electronics electrical appliances 占第二位.

 

type 别

Model/Grade

product features

未 reinforced grade

Zytel 103FHS

Zytel 105F

fast speed molding heat stabilized property nylon 66

UV resistant increase lubricating nylon 66

toughened grade

Zytel114BK97

Zytel408

impact resistant modified PA66

toughened PA66

toughened glass fiber reinforced grade

Zytel79G13L

Zytel80G14

13%GF, toughened PA66

14%GF, toughened PA66

flame retardant grade

ZytelFR70M30V0

ZytelFR70M40GW

30%矿 material reinforcement PA66, UL 94V-0(1.6mm)

40%矿 material reinforcement, hot rod 9601.5mm

DuPont company separation nylon 66 Model/Grade and features

 

5, PA6 and PA66

 

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PA6 and PA66 difference, its chemical material features versus 似, 但PA6 melting point relatively low, but also process temperature degree scope/range very wide, impact resistant property and resistant solvent understanding property more strong/high. 而阿斯顿马丁 for sheet/plate material requirements standards is PA6. lower 面我们 comparison lower PA6 and PA66 difference:

 

property can

PA66

PA6

structure mono 元

由 adipic acid hexamethylenediamine polycondensation

caprolactam polycondensation

melting point

high 达260

melting point relatively low, low 40℃ left right, process temperature degree scope/range very wide

heat resistant property

resistant thermal properties need good

resistant temperature 不理想

force property can

PA66 rigid property good, elastic property modulus more good

PA6 tough property good, impact resistant property and resistant solvent understanding property ratio PA66 need good

other property can

但染 color relatively difficult, easy upper color; relatively nylon 6 soft/flexible

吸 wet property more strong/high

application

轮胎帘子线 and heat resistant water 洗涤织 material and material, industrial gears upper use 螺旋桨

攀手, automotive structural parts

price

nylon 66 price ratio nylon 6

 

 

PA6 chemical material features and PA66 very versus 似, however, it melting point relatively low, but also process temperature degree scope/range very wide. it impact resistant property and resistant solvent understanding property ratio PA66 need good,但吸 wet property more strong/high. is parts many quality features need to wet property effect/influence, therefore use PA6 design product need separation to this 一点. is improve/increase PA6 machine features, add various modifier. 玻璃就 is most Common additives, has is high impact resistance property also add combined formed 橡胶, 如EPDM and SBR and other.

 

6, PA66 application 举例

 

due to nylon 66 excellent heat resistant property, chemical resistant product property, strong/high degree and processing and other, in automotive industrial to a large amount of application, currently already can used for automotive has 部位, 如发动 machine 部位, electrical appliances and 车体部位.

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