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glass fiber reinforced flame retardant high temperature nylon PA46 formulation
PA is large engineering plastics 之一, full scope/range 而言, it currently year amount 居于各 engineering plastics raw materials 首位. currently use PA90% above is PA6 and PA66, other PA, 如PA11, PA12 and PA46 and other in 一 特殊 application in important property positive day growth. high temperature resistance PA46国 inner 尚未见 production.
PA46 is 1989 year 首先由DSM company industrial production, currently company PA46 output/production volume 约20kt/a. in has PA in, PA46 亚甲基 and amine content most low, tool has very high crystallization degree, this features 赋予PA46极佳 heat resistant property, chemical stability property, resistant creep property, corrosion resistant property and excellent electrical properties, and surface electrical retardant, electrical strong/high degree and CTI value high. PA46 main/primary used for resistant temperature property, rigid property and dimensional stability requirements key/critical electronics electrical equipment and precision machine parts, but also requirements tool has relatively high flame retardant grade 别.
formulation formed:
formed 份 use amount
PA46(DSM) 47
glass fiber (GF) (巨石) 35
PBS-64HW 13
Sb2O3 4
other additives 1
extrusion process conditions:
temperature degree 290, 300, 305, 300, 295, 295℃
screw speed 200---250r/min
true degree >0.06MPa
injection molding process conditions:
temperature degree 315~320℃
pressure 40~75MPa
speed 30r/min
mold temperature 100~120℃
raw materials dry temperature degree 130℃
dry time 3h
in PA add 入30% glass fiber, PA force property can, dimensional stability, heat resistant property, resistant aging property can has obvious improve/increase, resistant fatigue strong/high degree is reinforcement 2.5 倍. glass fiber reinforcement PA engineering plastics raw materials molding process and reinforcement large same, flow relatively reinforcement front 差, therefore injection pressure and injection speed degree need improve/increase, machine temperature degree improve/increase 10-40℃. due to glass fiber (GF) in injection molding process in flow direction orientation, force property can and shrinkage rate in orientation direction upper reinforcement, products deformation warpage, therefore, mold design 时, gate 位置, need combined 理, process upper can improve/increase mold temperature degree, products rear hot water in let its slow cooling. another, add glass fiber (GF) ratio/proportion large, its for injection molding machine 塑化元 parts abrasion loss large, most good is using/adopting di metal screw, machine 筒.
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