Shanghai Daoqin Plastics Co., Ltd.

acrylic - styrene - propylene 睛（简称ASA）
ASA polymer is 无定形材 material, can using/adopting and injection molding processing made formed for gas effect/influence has good resistant force product. terpolymer ASA mechanical properties usually similar 于ABS resin, different is ASA property can outer gas effect/influence need ratio ABS resin small more.
chemical and property can
terpolymer ASA plastics raw materials can use has patent patent reaction process, or grafting process production. in reaction method in, ASA is through in styrene and propylene 睛（SAN） polymerization reaction process in 接技一 types acrylic ester elastomer made, elastomer fine powder uniform dispersion 入并接校 in SAN separation upper.
ASA杰出 weather resistance acrylic ester elastomer. for many plastics 而言, in day light especially is in light 谱 紫 outer 线一端辐射 and large gas in oxygen gas function lower, 会发生脆化 and 变黄. ASA部 parts this type of 变化 需 time ratio its it plastics long more.
ASA部 parts make in low temperature lower tool has very high light slip degree, very good chemical stability property and resistant thermal properties, and very high impact strong/high degree. ASA in 1．82MPa pressure lower, standards heat deflection temperature (HDT) is 180?220°F; resistant strong/high degree is 27．6～48．3MPa; fracture elongation is 25?40％; flexural modulus 1516～1723MPa; belt/tape 切口 悬臂梁式 impact strong/high degree is 9．0一11．0英尺?磅／英寸.
ASA can resistant lower material function: saturated and 烃, low 芳烃汽油 and lubricated 油, material and material 油, water, salt water solvent liquid, dilute acid and dilute alkali. however, it easy concentrated machine acid, 芳烃, chlorine 代烃, ester. ether, ketone and certain alcohol type 侵蚀. ASA ratio ABS has more good resistant ring force fracture property can. ASA材 material flame retardant grade is UL 94?HB.
specialized product
ASA also has and its it polymer has good mixed solvent property features, but also 以ASA is alloy and mixed combined material can make it weather resistance by has utilizing. acrylic specifications, amount and distribution 变化都 can formed different specialized products, tool has relatively high heat deflection temperature (HDT) HDT, low surface, or scratch resistant property can.
glass fiber reinforcement ASA／PBT thermoplastic plastics polyester, tool has excellent weather resistance, combined reinforcement PBT mechanical properties and thermal properties advantages, but also has good tough degree and dimensional stability.
processing
ASA resin can use large more 数传统 methods processing. this methods type and sheet/slice 材挤塑 and 共挤塑, injection molding, structure foam and pressure blow molding. sheet/slice can hot molding.
blow molding in has 槽, has cooling and hot insulation add material 段 挤 pressure machine in 进行. screw has deep 螺纹, decrease/reduce scratch hot. use belt/tape has material device pressure machine most good.
need ASA resin sheet/slice 进行预 drying. need in processing front, use 一 空 gas ring in 185°F lower sheet/slice drying 4?6 small 时. ASA部 parts can use hot welding technology; in certain combined, ultra- 声 welding is can can. ASA部 parts also can use 2一丁 ketone, chlorine ethylene or ring 己烷进行 solvent agent welding. use surface 预处理, parts very easy 接受并 maintain printing and coating 漆. can can use methods true metal.
applications
ASA杰出 weather resistance make it in lower field/area inner separation has use: construction field/area, used as water 槽, water tube/pipe and pipe fittings, 标志牌, 邮筒, light use sheet/plate, 花盆, 百叶窗 frame decoration.
休闲娱乐: outer furniture, sheet/plate, 游泳池泵 and device outer housing/shell, temperature 泉, water use and small 船.
automotive and 运输: outer 侧视镜 housing/shell 体, 托架. 保险杆封皮, decoration.
商业信息
现 has standards and use 户指定 color ASA resin product types scope/range very wide. color different, 1993 year 初 典 type wholesale is 1．70?2．00美元／磅.
market ASA basic resin grade has: Luran S牌（ BASF plastics material company ）; Gelog牌（ general purpose plastics company ）; Centrex牌（孟山都 company ）.

styrene resin ABS ternary polymer ABS
from 本世纪40 year 代开始商业化, amount year growth, already formed is full amount most large engineering thermoplastic property plastics, USA amount 就于1989 year ultra- 12 100 million 磅. in large product plastics and high property can engineering thermoplastic property plastics between, ABS占据 独特 “ 渡” polymer 位置.
chemical and property 质
ABS more can property it mono structure mono 元?? propylene 睛, butadiene and styrene. 每 组 separation is most polymer provide sleeve/set different has use property can. propylene main/primary provide chemical resistance and heat stabilized property; butadiene provide degree and impact strong/high degree; styrene separation is ABS provide hardness and can processing property. has types production process?? emulsion method, 连续本体 method or method, types process methods made ABS raw materials in styrene content is 50％甚至 more high. usually less types process combined use, make most material most 佳化. ABS resin belongs to versus system: styrene propylene copolymer （SAN） is versus, butadiene 衍生橡胶 is elastomer dispersion versus.
实际 upper also has a small amount of styrene and propylene in butadiene upper copolymer combined reaction （ grafting ）, 本 不 versus hard SAN and versus 容起. therefore, can ABS看 as is in upper formed polymer alloy 之一.
改变三 types mono 体A, B, S ratio/proportion, polymer molecular weight and versus 形态就 can has ABS product selection. 例如, versus pellets large small can from small 于0．1 micron to several micron. versus inner pellets large small and pellets large small distribution, for polymer property can overall 均衡, strong/high degree, tough degree and appearance has important effect/influence. large pellets increase tough degree reduce light slip degree.
and molecular weight related hard versus long degree for ABS resin property can has significantly effect/influence. generally, polymer long, strong/high degree property can （包括 impact and property ）越 high, flow property can low.
most rear, hard SAN versus and versus ratio rate will effect/influence ABS resin flow property and impact resistant property can between 均衡, 例如, content increase will improve/increase ABS材 material impact strong/high degree and tough degree, usually flow property is 代价. flow property can and impact resistant property can between is ABS材 material basic product 特征, this type of will general purpose ABS材 material difference 开.
alloy and specialized product
if in polymerization process in add more multiple mono 体, or mixed chemical additives, or and types plastics blending or formed alloy, can 进一步拓 wide 以ABS is resin property can scope/range.
例如, in polymerization process in add 入α一甲基 styrene or acid 酥, can production tool has relatively high heat deflection temperature (HDT) 以ABS is 基础 材 material. use methacrylic acid ester, can make hard versus and versus 折射指数 versus 匹配, from make material tool has transparent degree.
usually, ABS resin and additives in polymerization in as is most rear 一 工序进行配 material, or as is separation 别 工序 in pressure or 班伯里密炼 machine and other melt mixed combined equipment in 进行熔 melt material. use type additives can resistant outer property can and heat stabilized property, flame retardant property and anti-static property can. tool has more high strength and hardness reinforcement type ABS already 经商业化.

ABS has use features is can and various different polymer formed series alloy, this alloy tool has ultra- 出传统均衡 property can new property can scope/range.
most is ABS－一 polycarbonate (PC) (PC） alloy, and 基础ABS terpolymer versus ratio, it performance 出改进 impact resistant property can （ especially is in low temperature lower ） and high resistant thermal properties. it in automotive market, surface sheet/plate and 车 轮挡 sheet/plate and other has very strong/high suitable property. through add additives, PC／ABS alloy also can made formed flame retardant type material, already in use machine market upper very large formed 功. flame retardant type ABS材 material 另一 商业化途径 is and PVC组 formed alloy; PVC is tool has flame retardant property material.
ABS and types crystallization type polymer formed alloy, tool has more strong/high chemical stability property. already product has: ABSPBT（ terephthalic acid ester ） alloy and ABS nylon alloy, its target/goal market 包括草坪 and device tool, automotive internal material, force tool housing/shell and product packaging materials.
ABS alloy new series, can need chemical additives or filler （炭 or metal ）, 而显示 “永久” electrical dispersion property can. this type of anti-static property can is resistant scratch 拭, for temperature degree versus for 敏感.
this alloy 不风化并 has good color can force, application target/goal main/primary is material processing field/area. （ need to more more has 关ABS alloy material, 请参见本书第5页“ alloy and blending ”一章）.
processing
ABS is 无定形 thermoplastic plastics, it in temperature degree scope/range inner soft 化而不 is 突然熔化. ABS稍 tool wet property, in processing front 应予以 drying. ABS usually sheet/slice formed 出售, color is color, color or mixed combined color, has 以自然 powder formed 出售. can use concentrated shrink color material meet/satisfy most use 户 精确 requirements. various ABS材 material easy 于接受 commonly used processing 处理, machine processing, bonding, solid, electroplating, coating and other.
ABS resin basic long is processing properties. ABS材 material processing as conditions scope/range wide and tool has good dilute flow features. very more processing 形式都 can selection, injection molding, 挤塑, hot molding, structure foam and blow molding.
applications
ABS基 product property can scope/range wide 广, processing wide degree large, price and property can relatively 均衡, this make it application market very 广.
运输. this is ABS in USA most large market, year use 约3 100 million resin. automotive application very more, 包括车 inner and outer. is internal injection molding use, already development high heat resistant, general purpose and light slip property low material, used as surface sheet/plate, control sheet/plate and its it automotive internal 装演部 parts.
人们普遍认 is ABS is made as automotive internal parts plastics. external application 则包括 dispersion hot device 格栅, front lamp covers and large type use pressure hot molding methods made formed various belt/tape. electroplating grade ABS can used for 手, frame, base/seat, and decoration belt/tape.
device tool. 1989 year USA device tool market consumption 2．5 100 million 磅ABS resin, its in large separation consumption in main/primary device tool upper, pressure hot molding and 油罐衬里 is 首. transparent ABS used as 冰箱 冻结箱托架.
device tool market its it applications has use tool, force tool, true remove machine, machine and electrical 动头发吹风 machine upper use injection molding outer housing/shell. ABS受人偏爱 is due to it strong/high degree, tough degree, light slip degree. color force, processing properties and price and other between good balanced.
商 use machine. is ABS large “附 add value ” market, this separation in 1989 year is 7500万磅 resin, in history upper maintain strong/high growth speed degree. flame retardant grade material in machine outer housing/shell and control sheet/plate very suitable.
construction. ABS in field/area inner has application, especially is in water, waste water and gas （ combined 称DWV） tube/pipe, and injection molding pipe fittings and other 方面. 1989 year USA amount ultra- 1．5 100 million 磅. ABS材 material can and low price PVC in DWV pipe/tube market upper 共存, is due to it can provide low temperature impact property can, relatively easy bonding and low more specific gravity.
消费 product and industrial product market in has many separation application ABS. this toys, medical device tool, and use tool, furniture, product packaging, shipbuilding, 排灌, and 淋浴间. non 常美观. good processing properties, high light slip degree and has cost ／ property can between balanced and other requirements, ABS for/regarding this vast market separation combined property.
商业信息
尽 tube/pipe ABS use industrial standards 说, already has very long history, this category of product and its large more market and application, also has formed 熟. future year inner, USA for ABS resin demand expected will year 3～5％ speed degree growth.
ABS in Europe growth rate and USA versus 似, 而太平洋 区 versus is year 7～ 10％ left right. 以ABS is alloy ratio standards ABS resin expected has more fast growth.
in 1991 year in price table/sheet upper, general purpose 途ABS injection molding grade product price scope/range is: in impact ／原始 type resin is 1．47美元／磅; high impact strong/high degree grade material price is 1．62美元／磅.
generally, grade product need low 5％～ 10％. specialized flame retardant grade and high heat resistant grade is 回．65美元／磅, this is 原始材 material wholesale 价.
below/following is USA main/primary ABS production 商: general purpose plastics company （Cycolac牌 resin ）, 孟山都 company （Lustran）, Dow chemical company （Magnum牌）. general purpose plastics company （美）国 inner production can force most large, market 份额居先. has this supply has USA outer production can force.

polypropylene (PP) random copolymer
polypropylene (PP) random copolymer is polypropylene (PP) types, it polymer/macromolecule basic structure use add different types type mono separation add modified. ethylene is most commonly used mono 体, it polypropylene (PP) material property 质 改变. and PP homopolymer versus ratio, random copolymer optical property can （ increase transparent degree decrease/reduce 浊雾）, improve/increase impact resistant property can, increase property, reduce temperature degree, from reduce hot temperature degree; meanwhile in chemical stability property, water 蒸汽隔离 property can and device 官感觉 property can （ low odor and 味道）方面 and homopolymer basic same.
development will transparent degree and impact strong/high degree combined PP random copolymer, used for blow molding, injection molding, film and sheet/slice pressure processing field/area, as food packaging materials, packaging materials and day 常消费 product.
chemical
PP random copolymer generally has 1－ 7％（ weight ） ethylene separation and 99? 93％（ weight ） propylene separation 子. in polymer upper, ethylene separation random 则 插 in propylene separation in 间. in this type of random or statistics copolymer in, large more 数（ usually 75％） ethylene is mono separation 子插入 methods combined 进, 叫做X3基团（三 连续 ethylene ［CH2］依次排列 in upper ）, this also can formed is ethylene separation in propylene separation in 间.
另 has 25％ ethylene is more separation 子插入 methods combined 进主链, also 叫X5基团, is has 5 连续 亚甲基团（两 ethylene separation 子一起插 in propylene separation in 间）. very difficult X5 and more high 基团如X7, X9 and other add separation. 鉴于此, XS and more high ethylene content statistics is ＞X3％.
random degree ratio value X3／X5 can 测定. 当X3 above percentage very large 时, will significantly reduce copolymer crystallization degree, this for random copolymer most property can effect/influence very large. copolymer in high content ethylene for polymer crystallization degree effect/influence, similar high random polypropylene (PP) content function.
random PP copolymer different homopolymer, is random polymer in ethylene separation retardant polymer separation crystallization type 排列. copolymer crystallization degree reduce material property 质 改变: random copolymer and PP homopolymer versus ratio rigid degree reduce, impact resistant property can improve/increase, transparent degree more good. ethylene copolymer also has relatively low temperature degree, this formed it in certain application advantages.
random copolymer has relatively more can material and random PP, and ethylene content high more polymer 链. this type of relatively high can material content, different polymerization process, different degree in has product copolymer material in, in meet/satisfy food tube/pipe 理局（ FDA ） about/regarding food contact upper formed difficult.
manufacturing methods
ethylene ／ propylene random copolymer is ethylene separation and propylene separation meanwhile polymerization reaction made, use reaction device and production PP homopolymer 一样. ethylene separation ratio propylene separation small, reaction fast 于（ reaction active property 约十倍） propylene. this make catalytic agent 立体定 toward property decrease low active property increase large, from 而导致 random polypropylene (PP) formed amount increase more. is decrease/reduce this type of random material formed, need reduce reaction temperature degree, from reduce catalytic agent active property, decrease/reduce most material in random 异构体 content, to types tool has relatively property can product.
ethylene content high （＞3％） random copolymer in production process in 处理起 comparison difficult, very difficult in dilute agent in polymerization reaction, is reaction grade product （ random polypropylene (PP) and ethylene amount very high copolymer ） can solvent 于己烷. this in liquid propylene polymerization reaction is 一样, tube/pipe solvent understanding degree relatively low. dilute process production a large amount of product, must in again ring stage/phase separation 离出, this increase production cost, however can to combined a small amount of can solvent separation relatively polymer. in polymerization process in, this 杂质会留 in polymer in, in thin sheet/slice material belt/tape 麻烦. but also, most copolymer product in has relatively more can solvent property 杂质. use has machine solvent agent 进行二次清洗, can remove large separation 杂质, also improve/increase copolymer production cost. generally, material content high 时, thin sheet/slice random copolymer relatively viscous, ethylene content high 于3．5％（ weight ）时, this issues more 突出.
处理 issues increase more, and relatively low reaction device temperature degree random copolymer relatively low production speed degree. but also random copolymer production cycle usually very short. this factors make random copolymer production cost high homopolymer, for ethylene content high random copolymer more is 如此.
copolymer melting point reduce and ethylene content related. 据报导, ethylene content is 7％时, copolymer melting point low 达152°F. X3 content for copolymer melting point effect/influence ratio and more high content effect/influence more large. it also 取决于 catalytic agent 本身, and its 以X3基团代替以X5基团结 combined ethylene can force.
property can
physical properties: generally 说, random PP copolymer ratio PP homopolymer property good rigid property low. it in temperature degree drop 至32°F时, also can maintain in impact strong/high degree, temperature degree drop 至-4°F时, has use property has 限. copolymer flexural modulus （ 1％应变时 割线 modulus ） in 483～1034MPa scope/range inner, homopolymer in 1034～1379MPa scope/range inner. PP copolymer material molecular weight for rigid property effect/influence 不如PP homopolymer large. belt/tape 切口 悬臂梁式 impact strong/high degree generally in 0．8～1．4英尺?磅／英寸 scope/range inner.
chemical resistance can: random PP copolymer for acid. alkali, alcohol, low carbon hydrogen combined material solvent agent and many has machine chemical product function has very strong/high resistant force. room temperature lower, PP copolymer basic solvent large more has machine solvent agent. but also, 当暴露 in 肥皂, alkali liquid. water property agent and alcohol type in 时, it 们不象 its it many polymer that 样会发生 ring force fracture loss bad. and certain chemical product 接触时, especially is liquid 体烃. chlorine has machine material and strong/high oxidation agent, can surface cracks or solvent 胀. non property combined material generally ratio property combined material more easy is polypropylene (PP) absorption.
retardant property can: PP copolymer and homopolymer has very low water 蒸汽渗透 rate （0．5克／ milli rise ／100平方英寸／24 small 时）. this property can through toward add 以改进. tensile blow molding type polypropylene (PP) bottle already resistant water 蒸汽渗透 property can 改进至0．3, oxygen gas rate to 2500.
electrical property can: generally, polypropylene (PP) has very good electrical property can, 包括: high electrical strong/high degree, low dielectric constant and low loss consumption 因子; however, power/electricity application generally selection homopolymer.
applications
random copolymer type polypropylene (PP) main/primary used for film, blow molding and injection molding and other requirements high transparency degree combined. ethylene content relatively high copolymer, due to 熔接起始 temperature degree relatively low 而广泛 used as extrusion film structure 特殊密封层.

poly 邻苯二酰 amine
poly 邻苯二酰 amine （简称PPA） resin is for 苯二甲 acid or 邻苯二甲 acid is raw materials semi aromatic polyamide (PA). has semi crystallization 态, has non crystallization 态, its 玻璃化 temperature degree in 255°F left right. non crystallization PPA main/primary used for requirements retardant property can combined; semi crystallization PPA resin main/primary used for injection molding processing, used for its it melt processing process. lower main/primary introduction rear 者?? semi crystallization 态PPA resin, especially remove outer. semi crystallization 态PPAS melting point is 590°F, transparent 矩形切 sheet/slice supply.
property can
PPA resin ratio type polyamide (PA) nylon 6, 6 and other more 结实坚 hard; for water separation degree more low; thermal properties more good; but also creep, fatigue and chemical resistant product property can good more. 例如: 含 45％玻璃 short fiber PPA resin, resistant strong/high degree 约276MPa, flexural modulus ultra- 13786MPa, heat deflection temperature (HDT) （HDT）549°F. make material filler grade PPA, resistant strong/high degree can to 117MPa. PPA resin property nylon 6, 6, however, already development reinforcement impact modified grade PPA resin, its 缺口悬臂梁式 impact strong/high degree high 达20英尺?磅／英寸.
has poly amine absorption water separation, increase function and dimensions 改变. nylon 6, 6, in 23°F lower, versus for wet degree is 100％时, can absorption 8．9％ water separation, this make its 玻璃化 temperature degree 由6．5°C drop to 一20℃, dimensions increase 2．3％. in same conditions lower, PPA resin can absorption 约6% water separation, its 玻璃化 temperature degree Tg不会 low 于40℃, dimensions growth ultra- 1．0％.
positive front 面 提, use reinforcement PPA resin has very high HDT value, can resistant very high temperature degree short function, 例如: in 一 供炉 in or in versus and in outer 逆流团结 process in. PPA resin hot oxidation stability property make it can resistant long high temperature function, reinforced grade PPA, in 20 000 small inner, its use temperature degree can 达330°F.
in positive ring conditions lower, PPA resin usually for 脂肪烃, 芳香烃, chlorine 代烃, ester, ketone, alcohol and large more water solvent liquid performance excellent resistant solvent property. this category of resin can 经受极 strong/high acid and strong/high oxidation agent function. can solvent and 甲酚. PPA并 non flame retardant, according to UL 94 standards, flame retardant grade grade resin grade is VO, 直至0．031英寸 thick degree.
processing
尽 tube/pipe its it melt process can use, large more 数PPA resin is use injection molding method processing. PPA raw materials drying to low 于 0．1％ wet degree water 平, rear hot metal bag or box/case inner, this container can ensure PPA raw materials in processing front use again drying. processing process can wet degree water is 0．15％ or more low. processing wet resin can make molecular weight reduce, formed versus mechanical properties upper loss 失. use drying agent 贮斗式 drying device, in 175°F conditions lower very easy resin drying to wet degree 达一25°F甚至 more low. drying time absorption water amount 而定, generally in 4?16 small scope/range inner.