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history upper most comprehensive various type plastic raw materials material property application Knowledge 9
polyether 砜
polyether is types high temperature resistance, 无定形 thermoplastic property engineering plastics , it is from 1983 year upper tool has long heat stabilized property and many 芳族砜 典 type property 质. it can in many 方面取代 metal, 玻 璃以 and and other material.
property can
in polyether many applications in, most main/primary is it can in long high temperature conditions lower use. ASTM D? 648 heat deflection temperature (HDT) can 达 400°F.
it can in -148?392°F scope/range inner maintain very good tough property and property. 玻璃化转变 temperature degree is 428°F. in 60?106Hi frequency rate scope/range inner and in high temperature conditions lower, its electrical property can maintain 不变.
in room temperature conditions lower, its mechanical properties and its it type polymer versus 似. it is types hard material, flexural modulus is 2757MPa, tensile impact strong/high degree is 160 ft.-lb/sq.inch. mechanical properties stability property can maintain to will hot deformation temperature degree. polyether ratio its it 无定形 thermoplastic property plastics tool has more good resistant ring force crazing property can. property most strong/high is ester, ketone and type. has 一定侵蚀 property is alcohol, 芳烃.
polyether tool has hydrolysis stability property and resistant usually use acid, alkali. add flame retardant still tool has very good flame retardant property. it USA food material tube/pipe 理局( FDA )认 can can in food industry in one-time or more use.
polyether mixed combined material can is transparent, can is transparent. it has multiple glass fiber strong/high product grade. its it filling material 例如矿 material and micro can by using/adopting.
processing
polyether can in generally injection molding and extrusion molding equipment upper processing. polyether tool has versus high melt processing temperature degree scope/range ( most high is 610?750°F), this and it high heat deflection temperature (HDT) (400°F) has 关.
in melt processing front, must will its drying to water amount small 于 0.04%. this process can in 一 空 gas ring or material drying device inner formed, 300 °F drying 4 h or 350°F drying 2.5 h. is production low internal stress, high property can polyether products, injection molding mold temperature degree need to 300?350°F. inner flow property good, melt temperature degree is 725°F时, 0.08 in thick degree inner flow is 19 in.
application
due to polyether tool has very good heat stabilized property, therefore it non combined electronics, electrical appliances application. it can through high temperature welding plant/unit processing. its application 包括: formed electrical sheet/plate, connectors, lamp covers. filament box/case and automotive parts.
utilizing its flame retardant property, can production 运输工 tool parts hot molding housing/shell and composite/compounding material. use chlorine solvent liquid made composite/compounding material material is strip/profile very can 行 路线.
in processing in, polyether can many metal and products. pipe/tube, amount and and other.
polyether can use and polysulfone (PSU) versus electroplating process.
history upper most comprehensive various type plastics raw materials material property application Knowledge 4
polysulfone (PSU)
polysulfone (PSU) (PSO) is types transparent, high temperature resistance. stability high property can thermoplastic property engineering plastics. it tool has 无定形 property, low property, property small, in will 近玻璃化转变 temperature degree 374 °F时 still maintain very good electrical property can.
this property main/primary is polysulfone (PSU) separation structure in 二芳砜基团决定. this type of has from ring upper electronics trend. 砜基团 for oxygen 原子共振 and generate resistant oxidation property. high 共振也 make has reinforcement, make 基团形 formed structure. therefore in high temperature conditions lower, polymer tool has very good heat stabilized property and rigid degree. ether make separation tool has property, therefore tool has very good impact strong/high degree.
因 is 连接苯 ring tool has hydrolysis stability property, therefore poly machine easy hydrolysis and resistant acid, alkali solvent liquid.
polysulfone (PSU) (PSO) can through generally thermoplastic property plastics processing equipment processing, in high temperature conditions lower. in injection molding, extrusion, hot molding front, must for 之进行 drying.
property can
polysulfone (PSU) resistant acid, alkali, salt solvent liquid and resistant agent, and alcohol type, in has pressure high temperature conditions lower 也行. it resistant property solvent agent ketone, 卤代烃以 and 芳烃.
polysulfone (PSU) can in 300 °F蒸汽 in use. in 180°F water in, most large pressure is 13.8MPa(静态 negative 荷) and 17.2 MPa(间歇 negative 荷). is maintain long transparent property and impact resistant property 不变, 于180 °F water in, its most large pressure is 3. 5MP(静态 negative 荷), 6. 9MPa(间歇 negative 荷). water temperature degree low, its pressure high: in 72°F时, most large pressure is 20.7MPa静态 negative 荷), 24.7MPa(间歇 negative 荷).
in room temperature 20.7MPa pressure lower, 经 10000 h, polysulfone (PSU) creep (应变) has 1%. in 210°F, 2.07MPa force lower, 经 1 year rear, 总应变 still low 于2%.
in 300°F long use rear, polysulfone (PSU) strong/high degree and modulus increase 10%, insulation strong/high degree maintain 90%, impact resistant strong/high degree maintain 70%. polysulfone (PSU) tensile impact strong/high degree can 达200 ft.lb/in2. 当暴露 in high temperature lower several month in, 如300 °F会 generate 退火效应而 can reduce its 30% property can value. this property in year testing in maintain 恒定.
USA 保险商协会实验室定出 polysulfone (PSU) can in 320 °F lower use. due to it 玻璃化转变 temperature degree (Tg) is 374 °F, therefore it in use can more high temperature degree. Amoco company Udel牌 polysulfone (PSU) already by USA food and material tube/pipe 局( FDA )认 can and used for food industry, one-time or more application.
polysulfone (PSU) tool has very good comprehensive electrical property can: tube/pipe dielectric constant and loss consumption factors very low, still tool has high electrical strong/high degree and volume resistivity. and can in very temperature degree and frequency rate (甚至 micro frequency rate ) scope/range inner maintain 恒定不变.
poly can 进行镍 and copper chemical electroplating tool has 20 lb/in adhesion strong/high degree.
product grade
poly injection molding grade, grade in has transparent and transparent product. also has medical grade grade can combined USA XIX Class VI requirements.
application
polysulfone (PSU) widely used in need medical grade equipment parts.
polysulfone (PSU) in food processing equipment in application 包括: 蒸汽平锅, 咖啡滤 device, made machine tool, machine tool, 钳子, sheet/slice and tube/pipe 子.
polysulfone (PSU) in pipeline application in can metal, 包括阀门组 parts and pipeline parts. it tool has resistant chlorine gas, anti and other advantages.
polysulfone (PSU) can used for many semi film, 如肾透析. 反渗透 and ultra- 滤 and other.
electronics, electrical appliances application connectors, device. battery housing/shell 体, 开关, electrical container film and formed electrical sheet/plate.
in chemical processing equipment application in, used for 泵. sheet/plate, filler and anti pipe/tube.
商业信息
polysulfone (PSU) price pure resin from 4.25美元 to medical grade grade 每磅4.93美元.
has Amoco Performance Products company in USA 出售此 product. product is Udel.
thermoplastic property elastomer (TPE)
thermoplastic property elastomer this type of material tool has thermoplastic property plastics easy processing properties, also tool has hot solid property property 质. therefore, thermoplastic property elastomer can thermoplastic property plastics that fast speed, has 效, property processing products. this type of material currently in world upper for and thermoplastic property resin industrial has very large effect/influence.
20世纪50 year 代, thermoplastic polyurethane (TPU) (TPU). 60 year 代出现 styrene copolymer, to 70 year 代, also has many thermoplastic property elastomer versus 继问世.
full thermoplastic property elastomer use amount (1992 year is 800, 000 t/a) positive year 8~9% speed degree growth. expected this growth speed degree sustainable to 90 year 代. to 本世纪末, thermoplastic property elastomer will is formed product, that growth speed degree 会逐渐 decrease slow.
thermoplastic property elastomer is 橡胶, also is plastics. processing 而言, it is types plastics, according to property 质, it also is types 橡胶.
thermoplastic property elastomer tool has many excellent hot solid property features. its in 包括: 1. very less need 甚至不 need mixing/compounding; 2. processing process simple; 3. processing time short; 4. can consumption low; 5. can processing use material; 6. thermoplastic property elastomer products can use; 7. can more 经济, more fine control product quality; 8. density low; 9. can use plastics processing methods, blow molding, hot molding, processing.
当然 thermoplastic property elastomer in application in has 不足. 包括: 1. it belongs to new technology, 普通橡胶 processing for it 不熟悉; 2. thermoplastic property elastomer processing equipment hot solid property processing 厂不熟悉; 3.一 thermoplastic property elastomer need in processing front drying; 4. low hardness thermoplastic property elastomer can to more; 5. thermoplastic property elastomer in temperature degree rise high 时会熔化, make can used for short high temperature conditions lower; 6. has large amount production, can make thermoplastic property elastomer tool has property.
thermoplastic property elastomer Model/Grade
in in, thermoplastic property elastomer generally tool has 6 types Model/Grade. it is ( according to price and property can water 平排列): styrene 系嵌段 copolymer, polyolefin blending material (TPOS), elastomer type alloy, thermoplastic polyurethane (TPU) (TPUS), thermoplastic property copolymer ester and thermoplastic property polyamide (PA).
商 product thermoplastic property elastomer hardness from Shore A30至 Shore 75 D. product grade 数字随 hardness increase increase large. 并区随 hardness rise high, thermoplastic property elastomer type property can decrease low, plastics property can reinforcement. thermoplastic property elastomer use temperature degree scope/range is -95°F-340°F, and can in many different ring lower use. therefore thermoplastic property elastomer can hot solid property 橡胶, used for use hot solid property 橡胶 特殊 applications in.
processing
manufacturing processing thermoplastic property elastomer main/primary types methods is and injection molding, molding use less. through injection molding manufacturing processing thermoplastic property elastomer, fast speed also 经济. used for generally thermoplastic property plastics injection molding methods and equipment suitable for thermoplastic property elastomer.
thermoplastic property elastomer also can through blow molding, hot molding and hot welding processing. this methods can used for hot solid property products.
application
thermoplastic property elastomer application and generally hot solid property 橡胶一样广泛而 in-depth. 不, has 一 例 outer is gas 轮胎, currently 尚未找出 combined thermoplastic property elastomer. thermoplastic property elastomer applications has 实心轮胎, large small use device tool, construction material, 鞋. electrical insulation, sheet/plate 材, material and material packaging and use product. main/primary thermoplastic property elastomer in rear 文详述.
thermoplastic property elastomer ( elastic property ) alloy
thermoplastic property elastic type ( elastic property ) alloy tool has many excellent property can. types product, has hot solid property property can, tool has thermoplastic property resin property can, it can 代替橡胶, main/primary is due to it in processing upper excellent property. can 不经硫化, this improve/increase rate, decrease/reduce material make for mixing/compounding property drop most low. need make thermoplastic property elastomer can and competition, it need has low hardness, 空间柔曲 property and negative deformation, full 恢复形状 and other property can. for flexible plastics property can requirements and hot solid property 橡胶完 full different, is meet/satisfy this application need, alloy must need tool has rigid property ( flexural modulus ), impact tough degree and tensile strength and other features. it therefore can flexible plastics, is due to its tool has more excellent property can low temperature property, resistant creep property, elastic property 恢复以 and very good friction coefficient.
as is types thermoplastic property elastomer alloy?? thermoplastic property 硫化橡胶(TPVS), is 1981 year 问世. this type of material is and plastics mixed combined material, its in 橡胶部 separation by high degree 硫化. as is product has 乙丙橡胶 or 丁睛橡胶 and polypropylene (PP) (PP) mixed combined material, its in 硫化橡胶完 full by dispersion. high 效硫化 blending rear this type of mixed combined material and its it simple polymer blending material ( its in versus 未硫化, crosslinked or has separation 流化) is large same. thermoplastic property 硫化橡胶 property can can in manufacturing will full 硫化 橡胶(如EPDM)完 full dispersion in PP连续 versus in large large reinforcement.
also 报导 一 can blending 橡胶, 如天然橡胶 and crystallization property or semi crystallization property thermoplastic property plastics di blending system 例子.
mono versus system can melt processing elastomer alloy, is in 1985 year 问世. this type of new type material (MPR) is types combined formed elastomer, it tool has and plastics property 质, can use plastics processing equipment processing, can use 改进 橡胶 processing equipment processing.
this material has patent ethylene copolymer and chlorine polyolefin alloy, its in ethylene polymer already crosslinked. add increase agent and filling material can increase property and strong/high.
can melt processing in chemical property upper can design formed most tool has property. hot solid property 橡胶, has can melt processing polymer structure tool has very low crystallization degree, low flexural modulus, non good tensile deformation, force 一应变曲线 and chlorine 丁橡胶 and 丁腈橡胶 non versus 似.
most 近, injection molding product grade product has very large development, improve/increase flow property and injection molding can force. for/regarding this in and other viscosity polymer processing scope/range, ratio most product grade large large add wide. this material viscosity has 剪切依赖 property also has temperature degree property, this product in injection molding process in in 形状, dimensions, thick degree upper has 变化. products tool has relatively low shrinkage property, more good degree and excellent appearance.
property can
市面出售 elastic property alloy in hardness upper can to Shore A54一 Shore D50. product and other grade has generally applications and injection molding grade, flame retardant grade, FDA specifications grade and medical grade grade. tensile strength from 7.6~27.6MPa, flexural modulus can from 5.5(MPR) to 345MPa(TPVS).
usually, EPDM/PP TPVS以 its material 理, machine comprehensive property can 而闻名. soft/flexible grade specific gravity low, hardness scope/range wide, resistant pressure shrink deformation good and hot property good. thermoplastic property 硫化橡胶 various NBR/PP product grade is very good 胎橡胶 substitute/replace product. it tool has very good oil resistant material, resistant property. 丁基橡胶 and PP thermoplastic property 硫化橡胶 tool has low water property, gas property, and can melt processing 橡胶一样 can absorption can amount.
一 can melt processing property products tool has non good property can, and has soft/flexible property, decoration property and 手感. can melt processing products has 硫化橡胶 property can, tool has 不寻常 heat resistant, oil resistant, chemical resistant product and very good weather resistance. can melt processing can used as PVC modified, and can and certain thermoplastic property plastics processing, made formed composite/compounding material and type 材.
processing
processing thermoplastic property 硫化橡胶 equipment must can 够熔化, 塑化以 and melt resin mixed combined, therefore must tool has temperature degree and force obtain uniform temperature degree (至 less 350~370°F). using/adopting production that 如PE, PP, PVC and other general purpose equipment, can obtain very good 效果. it L/D ratio is 20: 1, or more large ( most good less is 24: 1). screw pressure shrink ratio is 3.0: 1~3.5: 1. machine temperature degree need to 350~400 °F. in processing front, hot gas drying is very necessary, especially is for thermoplastic property 硫化橡胶.
elastic property alloy in generally screw machine upper, can injection molding. it injection molding cycle short, demolding easy, and can production very good appearance and products. it can use standards injection molding or in blow molding equipment upper blow molding, can calendering, or is rear molding and hot welding. this material can use chemical or material property foaming agent foaming.
if can control temperature degree (320~350 °F), force and combined viscosity, 现代 橡胶 and plastics processing equipment can suitable for can melt processing 橡胶. therefore, many 现代 橡胶 extrusion machine, screw material 式橡胶 injection molding machine and 一 橡胶 calendering machine can add renovation use processing can melt processing 橡胶. plastics calendering machine, 往复式 screw injection molding machine and extrusion machine has high hot, can very easy by using/adopting. is use what methods renovation can melt processing production equipment, can maintain production plastics and can force.
tool has flow features can melt processing product can through lower methods processing: 挤塑. injection molding, blow molding, calendering, and hot molding. and, injection molding already by 简化; add wide low viscosity can melt processing scope/range, and make processing 需 特殊 requirements drop most low.
application
can melt processing main/primary used for made as 挤塑, molding, blow molding and calendering products. this product can use can melt processing 橡胶直接 made formed, can 由PVC and can melt processing blending material made formed.
can melt processing and selection PVC一 type thermoplastic property plastics processing, can to 预期 模塑 composite/compounding material and tool has rigid property and bending property thermoplastic property 组份 共 extrusion type 材.
迄今 large more by use can melt processing product large is products. 包括: construction material and automotive 窗密封 strip/profile, made cold device soft tube/pipe outer sleeve/set tube/pipe. cable 包皮, 门密封垫以 and 胶乳芯 rod. can melt processing 橡胶 挤塑一 blow molding product can used for production 回旋状 automotive 胎垫.
use can melt processing 橡胶模塑 various 形状 “橡胶” products most more. molding has large sheet/slice market field/area, it can meet/satisfy many different demand. expected new molding product will very fast by using/adopting. this type of molding product 包括: 支柱接头. liquid lower 阀门垫 sheet/slice, machine 插头垫( used for cable 口 密封), used for testing device precision A type 图, used for decrease 震 摩托车 gas 缸垫, used for and 封接 模塑 gasket, automotive water device sheet/slice, and and 门扶手组 parts.
thermoplastic property 硫化橡胶 in automotive parts, soft tube/pipe outer sleeve/set tube/pipe, 密封垫, 回旋状胎垫, 门窗密封 and other application in, non important. due to has very good electrical property can, therefore it by widely used in electronics, electrical appliances industrial in cable, electrical 线包皮. in many construction and structure applications in can used as 膨胀接头 and seals. product grade thermoplastic property 硫化橡胶 product can food. material, material and active 体组织. thermoplastic property 硫化橡胶 in 医学方面 application injection device, bottle 塞, mono and to material film and other.
商业信息
DU Pont company provide grade is Alcryn can melt processing raw materials and new easy molding product grade product. Monsanto company provide grade is Santoprene橡胶 and Geolast elastomer thermoplastic property 硫化橡胶.
thermoplastic property elastomer elastic property alloy price in and other, 1990 year 10 month 1 day price 每磅1.61~2.20美元 between. applications product grade product price high.
ethylene - acrylic ester (EEA)
ethylene - acrylic ester (EEA) resin is polyolefin in tough property and degree most large 一族. it scope/range from type 橡胶, combined as hot bonding agent low melting point product, to type polyethylene (PE), tool has non 同寻常 tough degree and degree product. this category of resin is ethylene and acrylic ester random copolymer, usually structure is
acrylic ester separation is copolymer provide degree and property, usually polymer 15?30%(wt) content. and ethylene -醋 acid ethylene ester (EVA) versus ratio, is ethylene copolymer, EEA has more high heat stabilized property, belongs to non property degradation product, can processing conditions scope/range more wide.
processing and again made 厂常常 EEA and type polymer or engineering polymer combined in 一起, production 出 两 types resin advantages combined product.
chemical and property can
EEA resin is in 专门改装 high pressure polyethylene (PE) reaction device in free radical polymerization method production. acrylic ester content increase 时, copolymer will more tough, more soft/flexible, more has elastic property. high acrylic ester content resin property, increase surface absorption ink can force tool has bonding property 质.
and its it polyolefin 如LDPE versus comparison, EEA basic use property can has: for force fracture, impact, and bending fatigue has relatively strong/high resistant force; relatively high friction coefficient; relatively good low temperature property can and more low melting point. acrylic ester (EA) content rise high 时, copolymer upper use temperature degree has decline, transparent degree reduce.
market upper EEA usually is add modified sheet/slice resin, has a large amount of filler specialized mixed combined material, flame retardant mixed combined material and used as coating semi 导体材 material.
processing
processing EEA copolymer can using/adopting is tool has versus melt flow index LDPE design standards 挤塑. blow molding and injection molding equipment. type pressure melt temperature degree is 320°F; injection molding method temperature degree scope/range is 280?400°F, specific value according to melt flow index and acrylic ester content 而定. EEA copolymer processing 时无论 using/adopting pressure method, blow molding method or injection molding method processing, usually must use additives.
applications
典 type applications 包括: polymer modified, hot property bonding agent and agent, property soft tube/pipe and tube/pipe 子, lamination sheet/slice 材, more film, injection molding and pressure parts and electrical and cable mixed combined material.
EEA copolymer can and has polymer versus 容, 如: VLDPE, LDPE. LLDPE, HDPE and polypropylene (PP) and other. EEA and its it polyolefin mixed in 一起, generally use production types modulus can to requirements, also 保留 想 need EEA features product. high modulus polymer poly lower difficult, amine and polyester, add EEA copolymer rear, impact resistant property can significantly improve/increase. EEA copolymer use production hot property bonding agent type product, ratio ethylene copolymer has more wide use temperature degree scope/range. EEA hot property bonding agent has 一 独特 comprehensive property can, 包括: very high 剪切破 bad temperature degree and low temperature tough degree; and for non property has excellent bonding force. in film application areas, EEA copolymer by used as more film 连结层, used for and its it polymer mixed 配以改进 low temperature tough degree and resistant force fracture property can. EEA copolymer for filler has very high nano amount, 以EEA and is raw materials semi film and pipe/tube by made formed micro type sheet/slice packaging materials, 甘油炸药 bag, and multiple 医院方面 anti-static applications. FDA 规定, food EEA copolymer in EA content can ultra- 8%, however, relatively high EA content copolymer can and its it polymer combined, from make mixed combined material in EA content low 于 8%, meet/satisfy FDA 规定. meanwhile, mixed combined material also must meet/satisfy FDA in 177?1520 strip/profile for polyolefin material made.
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