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history upper most comprehensive various type plastic raw materials material property application Knowledge 8
chlorine 化PVC
chlorine polyvinyl chloride (PVC) is polyvinyl chloride (PVC) resin rear chlorine to types polymer.
chemical and property 质
PVC separation upper again increase chlorine rear, material CPVC resin 玻璃化 temperature degree (Tg) will improve/increase 至239至275°F temperature degree scope/range inner; lower heat deflection temperature (HDT), according to its formulation different, will from PVC material material 约158°F improve/increase to 180至219°F temperature degree scope/range inner. is 说, outer increase chlorine, improvement hard PVC flame retardant property, property, improve/increase resistant strong/high degree and modulus, 而保留 it has good property can: dimensional stability, excellent chemical resistant features and good electrical property can.
CPVC mixed material plastics still maintain relatively high chlorine content resin high hot temperature degree features, its material material mixed process and PVC mixed versus similar, more complex, more difficult.
mixed material can application 传统 挤塑, calendering, injection molding and other processing pipe/tube, type 材, sheet/slice and other thermoplastic property molding methods. processing use di screw machine processing powder material material and use mono screw machine processing material material.
use types combined solvent agent solvent understanding CPVC resin, can made types very has use bonding agent. processing also can use its solvent liquid formed made CPVC流延 film.
processing
although CPVC is 以PVC is made polymer, and PVC共 has certain property can, is, it is types has its features polymer, this for/regarding its processing especially important. 例如, CPVC polymer melt temperature degree scope/range from 400°F直至 most high to 450°F. processing need using/adopting or 不锈钢 模头. 挤塑模头必 must is good type, ensure can long time processing 运转. sheet/plate 模头不 can obtain 满意 挤塑运转 time. is very good control pipe/tube and type 材 挤塑 dimensions, most good using/adopting true type technology. equipment 需配备至 less 40马 force screw plant/unit. has types screw design can 适于挤塑 processing various formulation good mixed material.
injection molding processing need using/adopting has combined 适导出 long degree low pressure shrink screw. pipe fittings use material material need using/adopting 尖梢式塑化 screw. low viscosity, high material material need using/adopting sliding ring processing screw, can using/adopting 球形止逆 screw. injection molding mold using/adopting 不锈钢材 material, less using/adopting or 镀镍材 material.
application
due to solid has chemical resistant features, high degree rigid property, solid has resistant property, excellent resistant strong/high degree, resistant inner light, resistant gas features and combined density, make CPVC材 material tool has application market.
传统 upper, CPVC材 material used for manufacturing cold. hot water pipe/tube, pipe fittings and industrial chemical liquid 体 传送 pipeline, pipe fittings, and other. most new technology development make can molding 窗玻璃镶装 pressure strip/profile, cooling sheet/plate, automotive inner use products, waste material device tool and various outer deep color application material product. 一 定 made injection molding product grade can office machine outer housing/shell, long 途通讯 equipment use product and 一 仪 device parts. most new development is anti system pipe/tube, pipe fittings use CPVC material material.
CPVC most 早( large 约1960 year ) used for manufacturing use cold, hot water tube/pipe and pipe fittings. its pipe/tube hot loss consumption low, water 滴, water poly 积, in 180°F temperature degree and 100磅/英寸2 pressure lower sustainable application, USA ring 境卫生基金会 can use water certification, 因而, make 数百万居住 small using/adopting CPVC pipe/tube. CPVC material material made formed water leading parts and used for use water system in, tool has advantages.
construction upper other application also 包括窗玻璃 deep color pressure strip/profile, frame 架, this is is CPVC has relatively high heat resistant property, can resistant deep color poly hot.
CPVC chemical resistant features make can used for industrial liquid 体, especially is 造纸, made process in high temperature liquid and electroplating, electrical chemical as in acid. alkali liquid 体. many electroplating industrial tube/pipe in using/adopting CPVC贮罐, pipe/tube and parts. also has pipeline, pipe fittings, 阀门, material sheet/plate and equipment, and other full use CPVC manufacturing system.
家 use electrical appliances manufacturing also 发现, CPVC良 good water property, solid has resistant property (达 to UL standards 94-SVA), resistant liquid, resistant property, for/regarding 直接安装 in machine, machine inner electrical machine upper water 泵 说, combined requirements.
high degree heat resistant property, resistant property, 遇油脂也不 crazing, can use CPVC manufacturing automotive inner parts. this features make CPVC can use manufacturing cold water tube/pipe and water 盘.
solid has resistant property ( UL standards 94?SVA can property ), and excellent chemical resistant features, UV resistant light property, resistant water and good property, make series new type Brand CPVC can use manufacturing printing machine outer housing/shell and base/seat and other type office machine parts.
also has low property CPVC material material, it meet/satisfy aviation specification 25.853款(A-1) has machine machine inner products hot value 必需符 combined speed rate most new requirements. meanwhile, this material material meet/satisfy 城市公共交通 tube/pipe 理局烟火准则 requirements. this low property material material products meet/satisfy inner A grade standards has low property can requirements. also has types deep color resistant gas new type Brand material material used for 农田灌溉方面. 总之, chlorine not only PVC原 has excellent property can, but also make polymer suitable for more high temperature degree lower, 因而, can metal or other price more engineering plastics.
商业信息
CPVC polymer The BF Goodrich company specialty polymer and chemical product separation company sales. 1991 year price is: 每磅1.30至1.50美元.
烯烃 modified styrene - acrylonitrile copolymer resin
烯烃 modified styrene - acrylonitrile copolymer resin (OSA) is tool has tough property engineering thermoplastic property plastics, in outer ring lower its physical properties and color 不发生变化. can design manufacturing various product grade modified styrene - acrylonitrile copolymer resin, or is used as production film or is will its 共挤塑 in various weather resistance 差, price low separation material surface, as is 保护覆 cover/cap 层. its it product grade OSA can sheet/slice or type 材, or injection molding.
chemical and property can
OSA is use saturated and elastomer modified styrene - acrylonitrile copolymer, again add outer light absorption agent. resistant oxidation agent, resistant gas aging material and other made. it tool has relatively high impact resistant strong/high degree and heat resistant property, in outer lower color 几乎不发生变化.
OSA resin resistant acid, alkali and salt, in many 石油馏 separation property 接触时 resistant property has 限. 建议不 need in and low molecular weight 芳烃, ketone, ester and chlorine has application combined use OSA product.
processing
OSA resin can used for blow molding film, sheet/slice or type 材, can injection molding. its processing conditions, rear positive, cooling and rear molding as must will internal stress control in most small degree, internal stress can effect/influence products resistant gas aging features. use long ratio is 24: 1 or more large 一 一段 or screw extrusion machine most 适宜. use standards type mold and material 头.
in OSA覆于ABS之 upper sheet/slice 材时共挤塑, in true molding 垂伸之 rear, its color OSA层 most thin separation thick degree less is 15mils. different upper film thick degree, separation 取决于底部基材. injection molding parts appearance again mold inner surface gloss 平整, outer 暴晒一, year rear, most high gloss formed product will formed light 毛面.
in production solid 态OSA resin 时, material use rate can is 25%. OSA as is cover/cap and resistant gas aging 基村共挤塑时, has can use material.
semi formed product parts can machine processing, 冲切, 钻孔, or use testing and OSA versus bonding agent assembly, can make used for OSA decoration technology hot 冲切, coating and use versus 容 材 material filament printing.
application
OSA as is 保护覆 cover/cap 层覆于 price relatively low 基材之 upper processing molding product parts its cost /效果 value relatively high, used for construction, use tool, and 运输以 and its it field/area in.
OSA and its it weather resistant polymer has versus property, can and it blending improvement property can.
history upper most comprehensive various type plastics raw materials material property application Knowledge 3
engineering use thermoplastic property elastomer
engineering use thermoplastic property elastomer (EngineeringTPES) is types high strength, high property can material. it elastic property ( elastic property 极限) and strong/high degree can 恢复程 degree in hard engineering plastics and between. it high elastic property in lower application in non use: in impact, 震动, bending rear, must fast speed 恢复形状??例如 automotive 保险杠, 铰链, elastic 簧, 卡扣, type, decrease device and flexible and 密封.
众 周知 engineering use thermoplastic property elastomer (ETES), tool has ratio more high strong/high degree ( generally is 2?6倍). therefore, in many application in, engineering use thermoplastic property elastomer can 代替橡胶 product, and 节省 材 material and processing time.
因 is engineering use thermoplastic property elastomer in thick or 支撑部位 upper “ function upper versus and other ”于 structure plastics, in thin also tool has elastic property; therefore it can in many application in as is more function material.
chemical
engineering use thermoplastic property elastomer flexural modulus from 34.5( large is rigid property 3倍) to 1379MPa( and nylon rigid property versus 似). in chemical structure upper, this type of resin is polyester crystallization hard and 无定形 binary alcohol soft random copolymer. hard and soft ratio/proportion can made formed series month 旨.
mechanical properties
engineering use thermoplastic property elastomer strong/high degree and rigid property separation is “典 type ” 橡胶( hardness is Shore A70) 2?6倍 and 3~100倍. generally engineering use thermoplastic property elastomer resin strong/high degree, rigid property and elastic property separation is strong/high nylon semi, separation and 三倍.
engineering use thermoplastic property elastomer elongation is 500%, elastic property is 7? 25%应变( based on different product grade ). this type of resin tool has relatively excellent bending lifespan, elastic property and resistant creep property. it can in very wide temperature degree scope/range inner maintain property 质不变.
动 force property can. engineering use thermoplastic property elastomer significantly is tool has non good force property can. combined design parts in 承受反复 tensile and pressure shrink rear, loss its mechanical properties, and can 承受数百万次 bending ring (甚至 in -40°F low temperature lower ).
impact resistant strong/high degree. this type of resin make in low temperature lower, tool has very good tough property. soft more 富柔曲 property product grade engineering use thermoplastic property elastomer, in standards 实验室 use 悬臂梁 impact testing in fracture, and can as is polyester, ethylene resin, polypropylene (PP) acid ester and styrene plastics impact resistant modifier.
temperature degree. engineering use thermoplastic property elastomer in 一40~300°F temperature degree scope/range inner, property can very good. mechanical properties from low temperature to very high temperature degree scope/range inner, ratio its it thermoplastic property elastomer and many 橡胶材 material more is stability.
other property can
electrical property can. engineering use thermoplastic property elastomer in 600伏 conditions lower has very good insulation strong/high degree. in low pressure in, use separation insulation thick degree, engineering use thermoplastic property elastomer can crosslinked polyethylene (PE) product. therefore, is in property can upper also is in upper, is very has 收益.
燃烧 property modified engineering use thermoplastic property elastomer is UL HB grade; add additives mixed grade separation is UL 94-2 and UL V一0 grade.
chemical resistant product and resistant ring effect/influence property. engineering use thermoplastic property elastomer resin tool has high degree chemical resistant product and heat resistant property. in hot type ring in, high rigidity product grade engineering use thermoplastic property elastomer property can most 佳; non combined in hot 油, 油脂, 燃油以 and liquid pressure in use. engineering use thermoplastic property elastomer also tool has for material low property. engineering use thermoplastic property elastomer resistant property, in can engineering use and medical grade products (灭菌)时, tool has very large excellent property.
weather resistance. engineering use thermoplastic property elastomer need 避免紫 outer 线照射. anti outer add material and concentrated material can in molding machine upper through amount blending by add 入. through year testing material 显示: 经 适当 stability resin, in various gas conditions lower can use.
processing
engineering use thermoplastic property elastomer must in processing front drying. it processing very easy 进行, processing conditions scope/range very wide. can use standards injection molding machine, machine, blow molding machine, molding machine and other. can through 挤塑铸塑 and blow molding made film. due to this type of resin tool has flexible, therefore in ejection must anti its pressure shrink and deformation. therefore, use tool has large type and film sheet/plate, and belt/tape has rod large force plant/unit.
独特 processing process 包括:
1. large type 倒置式 mold can using/adopting simple type and design 以便模 made complex products.
2.不需特殊处理便 can made formed overall active 动节点.
3. in 同一部 parts upper, can has thick thin different 截面.
4. and PVC, ABS, polyester and polypropylene (PP) acid ester has extrusion and 镶嵌模塑 versus property.
engineering use thermoplastic property elastomer resin in 模塑时 can to heavy mold surface A grade light degree. this 样不需二次 processing 处理便 can production coating automotive parts.
application
due to engineering use thermoplastic property elastomer meanwhile tool has mechanical properties, resistant ring effect/influence, easy processing and processing more property, therefore it can many material. 包括: metal, leather, and 铸塑, reaction injection molding (RIM) polyurethane ester. use it manufacturing product main/primary has: automotive parts, industrial product, general purpose tool. product, 通讯, equipment and medical grade products.
in coating automotive external parts 方面, new market. 包括: table/sheet sheet/plate, 保险杠 outer 皮, and 贴面包覆层 and other. its main/primary causes is engineering use thermoplastic property elastomer price low 廉, surface property can good and excellent resistant use property and other.
另一 types new trend is “ can injection molding leather ”. most substitute/replace leather is in made 鞋业. engineering use thermoplastic property elastomer can injection molding formed and leather 质, versus products, and tool has 便于缝纫 and bonding high strong/high degree.
商业信息
engineering use thermoplastic property elastomer positive in speed growth, design and manufacturing for this resin more add 熟悉而继续 growth. product engineering use thermoplastic property elastomer Du Pont company Hytrel Polymers ZytelFN flexible nylon alloy and used for automotive parts Bexloy V; Eastman Chemical company Ecdel; Hoechst Celanese company Riteflex以 and GE Plastics company Lomod and other and other.
styrene -马 acid copolymer
styrene -马 acid random copolymer is through using/adopting production polystyrene (PS) (PS) technology manufacturing 出. it in important automotive inner structure parts application 方面, as is most tool has property product by using/adopting; meanwhile, in 工, in, to use. new application positive by development, has micro food box/case, long glass fiber is 基础材 material structure parts and and styrene -马 acid copolymer blending material.
chemical and property can
most simple transparent styrene -马 acid copolymer (S?MA) is through styrene mono and a small amount of acid mono reaction made, 见图一1. acid mono random to PS主链 upper, increase 玻璃化转变 and heat deflection temperature (HDT). generally styrene -马 acid copolymer product heat deflection temperature (HDT) ultra- 260°F. in injection molding 时, make temperature degree ultra- 550°F时, this type of polymer property can still versus stability.
in reaction stage/phase, 橡胶段接校 in polymer upper, can make tool has very good tough property. in many engineering application in, is meet/satisfy tough degree requirements, this process is important.
in many application in, need through glass fiber strong/high increase styrene -马 acid copolymer strong/high degree and hardness. in through chemical methods glass fiber surface and high property acid separation between, chemical combined can very easy and resistant 久. this type of good bonding can through electronics micro 镜观察 its composite/compounding material 断口, to separation 证实. this type of bonding property can make its strong/high degree, modulus, tough property (甚至 long 期暴露 in poor ring lower ) maintain long 期不变. property can stability product, in temperature degree ultra- 235°F, 经 2000hr rear, its main/primary strong/high degree and tough property 几乎没 has loss 失. styrene -马 acid copolymer made formed automotive external parts, in automotive use lifespan inner, separation ensure safety property. this is important.
product types and property can
实际 upper, has 一 厂 toward world supply styrene -马 acid copolymer. can to its it styrene copolymer and terpolymer has styrene - propylene copolymer, styrene - methacrylic acid ester copolymer and styrene - methacrylic acid ester -马 acid terpolymer. this type of polymer impact property improvement generally can through and grafting ABS polymer mixed combined obtain. its it styrene polymer product types in market has 售 包括: and methacrylic acid or many different amine copolymer, has has and propylene copolymer made formed product.
is meet/satisfy many application areas made structural parts need, glass fiber strong/high for styrene -马 acid copolymer resin mechanical properties effect/influence non important. different product grade product tool has different strong/high degree, heat resistant property and tough property. currently, large more strong/high glass fiber content is 20%( weight ), its scope/range can in 5? 40% between. usually obtain 玻璃补 strong/high methods is mixed combined melt resin pellets and glass fiber. rigid rigid new type reinforcement thermoplastic property plastics ( glass fiber content ultra- 50%), make this resin more tool has made as structural parts excellent property.
没 has strong/high styrene -马 acid copolymer resin can has different transparent property, impact resistant property and heat resistant property. impact property improvement rear product tool has tough property and transparent property. has resin can and improve/increase heat resistant, weather resistance stabilizer 进一步 mixed combined, and can in many application in, formed different color. this type of resin is pellets 形, injection molding, 挤塑, foam 挤塑, structure foam molding, and can as is solvent agent type 填缝组 separation in viscous material. this product high melt flow for/regarding complex parts has fast speed molding cycle, is non 常理想.
processing methods and property can
injection molding. styrene -马 acid copolymer resin high melt flow property and fast speed type features make can fast speed injection molding. this improve/increase molding product rate, from large large reduce cost.
styrene -马 acid copolymer resin tool has non good features, this can make very easy injection molding and molding. rise high melt temperature degree from 440 to 550°F, can improve/increase flow speed rate 达 66%.
styrene -马 acid copolymer usually in 往复式 screw injection molding machine upper processing, screw pressure shrink ratio is 20: 1?25: 1. type screw L/D ratio is 15: 1?24: 1. used for AB巳PS, PC generally applications screw can use. gas and amount screw injection molding is non has 效.
use use material, can large large reduce cost. in large more application in, use material use amount high 达 25%时 for molding processing made parts property 质不会受 to loss 失.
挤塑. styrene -马 acid copolymer resin usually can use processing HDPS, PS, ABS resin mono screw or di screw extrusion sheet/slice production upper processing. styrene -马 acid copolymer can and different polymer 进行共挤塑. its products can used for many high temperature packaging in. in certain lower, through acid can hydrophilic combined force 而自行 bonding.
foam sheet/plate molding can use injection molding foaming molding technology, in generally 串联挤塑 machine upper 进行. foaming agent by injection to 主挤塑 machine amount 段. generally used for 挤PS foam screw can suitable.
application
from device sheet/plate to sheet/plate 衬里, from and 顶部 托架 to tool and trim parts, styrene -马 acid copolymer resin is automotive design 师认定 can as is internal parts. high thermal properties, very good hardness and dimensional stability and very high impact resistant strong/high degree and other excellent property can, in automotive application in, separation ensure safety (无论 is in high speed or low speed, high temperature or low temperature conditions lower 碰撞).
USA automotive manufacturing commonly used flexible table/sheet sheet/plate, is use mono block structure, 4~8lb heavy molding sheet/plate made. currently, styrene -马 acid copolymer resin table/sheet sheet/plate market has rate can 达40%.
due to styrene -马 acid copolymer resin tool has high temperature resistance property, very good hardness and dimensional stability, therefore it combined many 工, 商业材 material standards.
another, due to styrene -马 acid copolymer resin tool has wear resistance, high gloss degree, easy molding and very good decoration property, therefore its products not only resistant use, but also 美观, cost low. its application 包括: food use pallet, micro pallet, 空调栅格以 and safety machine 滚筒.
商业信息
styrene -马 acid copolymer industrial production already 达15 year, output/production volume ultra- 5千万磅, and positive year 15~ 20% speed degree increase. it widely used in automotive industry.
styrene -马 acid copolymer types material?? styrene and acid 团, is chemical product. polymerization processing can has production 出经济 基础 polymer.
也 has styrene -马 acid copolymer product grade. 包括: color stability 化处理. types important styrene copolymer product in market in and styrene -马 acid copolymer has similar applications.
styrene is copolymer tool has property can. in styrene -马 acid copolymer resin and styrene - methacrylic acid ester -马 acid ternary copolymer resin in acid increase styrene copolymer resin heat resistant property.
ARCO chemical company is USA provide styrene -马 acid copolymer resin product 厂商, product is Dylark Resin.
Monsanto chemical company provide and ABS resin use series terpolymer, product is cadon.
polyether 砜
polyether is types high temperature resistance, 无定形 thermoplastic property engineering plastics, it is from 1983 year upper tool has long heat stabilized property and many 芳族砜 典 type property 质. it can in many 方面取代 metal, 玻 璃以 and and other material.
EN
